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Beilstein J. Org. Chem. 2016, 12, 531–536, doi:10.3762/bjoc.12.52
Graphical Abstract
Figure 1: Halogenated anthraquinones.
Scheme 1: Initially proposed synthetic scheme for proisocrinins 6–11.
Scheme 2: Synthesis of cyanophthalide 12.
Scheme 3: Synthesis of cyclohexenone 13.
Scheme 4: Darzens condensation route to proisocrinins.
Scheme 5: Synthesis of cyclohexenone 36.
Scheme 6: Synthesis of the proisocrinin core structure.